Transcription

SAFETY DATA SHEETIssuing Date January 5, 2015Revision Date NewRevision Number 01. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKINGProduct identifierProduct NameKingsford Odorless Charcoal LighterOther means of identificationSynonymsNoneRecommended use of the chemical and restrictions on useRecommended useFuel for lighting charcoalUses advised againstNo information availableDetails of the supplier of the safety data sheetSupplier AddressThe Clorox Company1221 BroadwayOakland, CA 94612Phone: 1-510-271-7000Emergency telephone numberEmergency Phone NumbersFor Medical Emergencies, call: 1-800-446-1014For Transportation Emergencies, call Chemtrec: 1-800-424-9300Page 1 / 10

Kingsford Odorless Charcoal LighterRevision Date New2. HAZARDS IDENTIFICATIONClassificationThis chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200).Aspiration toxicityFlammable liquidsCategory 1Category 3GHS Label elements, including precautionary statementsEmergency OverviewSignal wordDangerHazard StatementsMay be fatal if swallowed and enters airwaysFlammable liquid and vaporAppearance Clear, colorlessPhysical State LiquidOdor Petroleum solventPrecautionary Statements - PreventionKeep away from heat/sparks/open flames/hot surfaces. - No smokingKeep container tightly closedGround/bond container and receiving equipmentUse explosion-proof electrical/ventilating/lighting equipmentUse only non-sparking toolsTake precautionary measures against static dischargeWear eye protection such as safety glasses.Precautionary Statements - ResponseIf swallowed: Immediately call a poison control center or doctor.Do NOT induce vomiting.If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water.In case of fire: Use dry chemical, carbon dioxide (CO2), foam, or water fog to extinguish.Precautionary Statements - StorageStore locked up.Store in a well-ventilated place. Keep cool.Precautionary Statements - DisposalDispose of contents in accordance with all applicable federal, state, and local regulations.Hazards not otherwise classified (HNOC)Vapors may cause irritation to the nose, throat, and respiratory tract. Repeated or prolonged exposure to concentrations abovethe Worker Exposure Limit may cause central nervous system depression (e.g. dizziness, weakness, nausea, headaches and/orunconsciousness).Solvents similar to those contained in this product have caused adverse kidney effects in male rats after prolonged and repeatedinhalation exposure. Reports have associated repeated and prolonged occupational exposure to solvents with permanent brainand nervous system damage.Page 2 / 10

Kingsford Odorless Charcoal LighterRevision Date NewUnknown ToxicityNone of the mixture consists of ingredients of unknown toxicity.Other informationPreexisting eye, skin, and respiratory disorders may be aggravated by exposure to this product.Intentional misuse by deliberately concentrating and inhaling contents may be harmful or fatalInteractions with Other ChemicalsReacts with strong oxidizers.3. COMPOSITION/INFORMATION ON INGREDIENTSChemical NameCAS-NoWeight %Trade SecretPetroleum distillates, hydrotreated light64742-47-8100No* The exact percentage (concentration) of composition has been withheld as a trade secret.4. FIRST AID MEASURESFirst aid measuresGeneral AdviceShow this safety data sheet to the doctor in attendance.Eye ContactHold eye open and rinse slowly and gently with water for 15 - 20 minutes. Remove contactlenses, if present, after the first 5 minutes, then continue rinsing eye. Call a poison controlcenter or doctor for treatment advice.Skin ContactWash skin with soap and water. If irritation persists, call a doctor.InhalationMove to fresh air. If irritation or breathing problems develop, call a doctor.IngestionDO NOT INDUCE VOMITING. Call a doctor or poison control center immediately.Aspiration hazard if swallowed - can enter lungs and cause chemical pneumonitis. Ifvomiting occurs, lean victim forward to reduce the risk of aspiration.Protection of First-aidersAvoid contact with skin, eyes, and clothing. Use personal protective equipment asrequired. Wear personal protective clothing (see section 8).Most important symptoms and effects, both acute and delayedMost Important Symptoms andEffectsVapors may cause irritation to the nose, throat, and respiratory tract. Inhalation of highconcentrations of vapors may cause central nervous system depression (e.g. dizziness,weakness, nausea, headaches, and/or unconsciousness).Indication of any immediate medical attention and special treatment neededNotes to PhysicianTreat symptomatically.Page 3 / 10

Kingsford Odorless Charcoal LighterRevision Date New5. FIRE-FIGHTING MEASURESSuitable Extinguishing MediaUse dry chemical, carbon dioxide (CO2), foam, or water fog to extinguish. Do not use a direct stream of water.Unsuitable Extinguishing MediaUse of water spray may be inefficient.Specific Hazards Arising from the ChemicalFlammable.Explosion DataSensitivity to Mechanical ImpactNone.Sensitivity to Static DischargeYes.Protective equipment and precautions for firefightersAs in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and fullprotective gear.6. ACCIDENTAL RELEASE MEASURESPersonal precautions, protective equipment and emergency proceduresPersonal PrecautionsAvoid contact with skin, eyes, and clothing. Ensure adequate ventilation. Use personalprotective equipment as required. Eliminate all potential sources of ignition. Takeprecautionary measures against static discharges.Other InformationRefer to protective measures listed in Sections 7 and 8.Environmental precautionsEnvironmental PrecautionsPrevent entry into waterways, sewers, basements, and confined areas.Methods and material for containment and cleaning upMethods for ContainmentPrevent further spillage if safe to do so. Absorb with non-combustible absorbent material.Keep out of drains, sewers, ditches, and waterways.Methods for Cleaning UpRemove heat and ignition sources. Absorb and containerize. Do not wash down tosanitary sewer.7. HANDLING AND STORAGEPrecautions for safe handlingHandlingHandle in accordance with good industrial hygiene and safety practice. Avoid contact witheyes, skin, and clothing. Avoid breathing vapors. Keep away from heat, sparks, openflames, and hot surfaces. Do not eat, drink, or smoke when using this product. To avoidvapor ignition by static electricity discharge, all metal parts of equipment must be grounded.Conditions for safe storage, including any incompatibilitiesStorageStore in accordance with NFPA 30B for Class II combustible liquids. Store locked up in awell-ventilated and dry area away from open flames, heat sources, and other ignitionsources.Incompatible ProductsStrong oxidizers.Page 4 / 10

Kingsford Odorless Charcoal LighterRevision Date New8. EXPOSURE CONTROLS/PERSONAL PROTECTIONControl parametersExposure GuidelinesChemical NameACGIH TLVOSHA PELNIOSH IDLHPetroleum distillates,hydrotreated light64742-47-8TWA - 100 ppmbbBased on TWA for StoddardsolventTWA - 500 ppmddBased on TWA for StoddardsolventIDLHe - 20000 mg/m3Ceilinge - 1800 mg/m3 (15 min)TWAe - 350 mg/m3eBased on limits for StoddardsolventACGIH TLV: American Conference of Governmental Industrial Hygienists - Threshold Limit Value. OSHA PEL: Occupational Safety and HealthAdministration - Permissible Exposure Limits. NIOSH IDLH: Immediately Dangerous to Life or Health.Appropriate engineering controlsEngineering MeasuresShowersEyewash stationsVentilation systemsIndividual protection measures, such as personal protective equipmentEye/Face ProtectionWear safety glasses. None required for consumer use.Skin and Body ProtectionWear rubber or neoprene gloves if there is the potential for repeated or prolonged skincontact.Respiratory ProtectionNo protective equipment is needed under normal use conditions. If exposure limits areexceeded or irritation is experienced, NIOSH/MSHA approved respiratory protection shouldbe worn. Respiratory protection must be provided in accordance with current localregulations.Hygiene MeasuresHandle in accordance with good industrial hygiene and safety practice. Do not eat, drink,or smoke when using this product. Do not wear product-contaminated clothing forprolonged periods. Wash hands after handling product.Page 5 / 10

Kingsford Odorless Charcoal LighterRevision Date New9. PHYSICAL AND CHEMICAL PROPERTIESPhysical and Chemical PropertiesPhysical StateAppearanceColorLiquidClearColorlessOdorOdor ThresholdPropertyValuespHNot applicableMelting/freezing pointNo data availableBoiling point / boiling rangeNo data availableFlash Point 40 CEvaporation rateNo data availableFlammability (solid, gas)No data availableFlammability Limits in AirUpper flammability limit 5.6%Lower flammability limit 0.8%Vapor pressure 2 mm Hg) at 20 CVapor density 4.9 at 101 kPa (Air 1)Specific Gravity 0.78 @ 15 CWater SolubilityInsoluble in waterSolubility in other solventsNo data availablePartition coefficient: n-octanol/water No data availableAutoignition temperatureNo data availableDecomposition temperatureNo data availableKinematic viscosityNo data availableDynamic viscosityNo data availableExplosive PropertiesNot explosiveOxidizing PropertiesNo data availableOther InformationSoftening PointVOC Content (%)Particle SizeParticle Size DistributionRemarks/ MethodNone knownNone knownNone knownNone knownNone knownNone knownNone knownNone knownNone knownNone knownNone knownNone knownNone knownNone knownNone knownNone knownNone knownNone knownNo data availableNo data availableNo data availableNo data available10. STABILITY AND REACTIVITYReactivityReacts with strong oxidizers.Chemical stabilityStable under recommended storage conditions.Possibility of Hazardous ReactionsNone under normal processing.Conditions to avoidFlames, heat sources, and ignition sources.Incompatible materialsStrong oxidizers.Hazardous Decomposition ProductsOxides of carbon.Page 6 / 10Petroleum solventNo information available

Kingsford Odorless Charcoal LighterRevision Date New11. TOXICOLOGICAL INFORMATIONInformation on likely routes of exposureProduct Information.InhalationInhalation may irritate nose, throat, and respiratory tract. Inhalation of high concentrationsof vapors may cause central nervous system depression (e.g. dizziness, weakness,nausea, headaches, and/or unconsciousness).Eye ContactMay cause temporary eye irritation.Skin ContactRepeated exposure may cause skin dryness or cracking.IngestionSmall amounts of liquid aspirated into lungs can cause chemical pneumonitis, which can befatal.Component InformationChemical NamePetroleum distillates,hydrotreated light64742-47-8LD50 OralLD50 DermalLC50 Inhalation 5 g/kg (Rat) 2 g/kg (Rabbit) 5.2 mg/L (Rat, 4 h)Information on toxicological effectsSymptomsVapors may cause irritation to the nose, throat, and respiratory tract. Liquid may irritateeyes and skin. Inhalation of high concentrations of vapors may cause central nervoussystem depression (e.g. dizziness, weakness, nausea, headaches and/orunconsciousness).Delayed and immediate effects as well as chronic effects from short and long-term exposureSensitizationNo information available.Mutagenic EffectsNo information available.CarcinogenicityContains no ingredient listed as a carcinogen.Reproductive ToxicityNo information available.STOT - single exposureNo information available.STOT - repeated exposureChronic ToxicityTarget Organ EffectsNo information available.No information available.Respiratory system, central nervous system, eyes.Aspiration HazardRisk of serious damage to the lungs by aspiration. May be harmful or fatal if swallowed.Numerical measures of toxicity - Product InformationThe following values are calculated based on chapter 3.1 of the GHS documentNo information available.Page 7 / 10

Kingsford Odorless Charcoal LighterRevision Date New12. ECOLOGICAL INFORMATIONEcotoxicityThe environmental impact of this product has not been fully investigated.Persistence and DegradabilityNo information available.BioaccumulationNo information available.Other adverse effectsNo information available.13. DISPOSAL CONSIDERATIONSDisposal methodsDispose of in accordance with all applicable federal, state, and local regulations.Contaminated PackagingDispose of in accordance with all applicable federal, state, and local regulations.14. TRANSPORT INFORMATIONDOTNot restricted in non-bulk containers less than 119 gallons.TDGExempt from TDG regulations in containers less than 454 liters per TDG regulations, Part 1,Section 1.33.ICAOUN-NoProper Shipping NameHazard ClassPacking GroupDescriptionUN1268PETROLEUM DISTILLATES, N.O.S.3IIIUN1268,PETROLEUM DISTILLATES, N.O.S., 3, PG IIIIATAUN-NoProper Shipping NameHazard ClassPacking GroupDescriptionUN1268PETROLEUM DISTILLATES, N.O.S.3IIIUN1268,PETROLEUM DISTILLATES, N.O.S., 3, PG IIIIMDG/IMOUN-NoProper Shipping NameHazard ClassEMs No.Packing GroupDescriptionUN1268PETROLEUM DISTILLATES, N.O.S.3F-E, S-EIIIUN1268,PETROLEUM DISTILLATES, N.O.S., 3,PG IIIPage 8 / 10

Kingsford Odorless Charcoal LighterRevision Date New15. REGULATORY INFORMATIONChemical InventoriesTSCADSL/NDSLAll components of this product are either on the TSCA 8(b) Inventory or otherwise exemptfrom listing.All components are on the DSL or NDSL.TSCA - United States Toxic Substances Control Act Section 8(b) InventoryDSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances ListU.S. Federal RegulationsSARA 313Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain anychemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372SARA 311/312 Hazard CategoriesAcute Health HazardChronic Health HazardFire HazardSudden Release of Pressure HazardReactive HazardYesYesYesNoNoClean Water ActThis product does not contain any substances tha