Transcription

Safety Data SheetPage 1 of 10BONDERITE C-IC 33 ACID CLEANER known as ALUMIPREP3320LTSDS No. : 319297V001.4Date of issue: 22.01.2016Section 1. Identification of the substance/preparation and of the company/undertakingBONDERITE C-IC 33 ACID CLEANER known as ALUMIPREP 33Product name:Etch CleanersIntended use:Supplier:Henkel Australia Pty Ltd135-141 Canterbury RoadKilsyth, Victoria, 3137AustraliaPhone: 61 (3) 9724 6444Emergency information:24 HOUR EMERGENCY CONTACT NUMBER: 1800 032 379Section 2. Hazards identificationClassification of the substance or mixtureHazardous according to the criteria of Safe Work Australia.GHS Classification:Hazard ClassCorrosive to metalsSkin corrosionSerious eye damageHazard CategoryCategory 1Category 1BCategory 1Hazard pictogram:Signal word:Danger20LT

SDS No.: 319297V001.4BONDERITE C-IC 33 ACID CLEANER known asALUMIPREP 3320LTPage 2 of 10H290 May be corrosive to metals.H314 Causes severe skin burns and eye damage.Hazard statement(s):Precautionary Statement(s):Prevention:P234 Keep only in original container.P260 Do not breathe vapors, mist, or spray.P264 Wash hands thoroughly after handling.P280 Wear protective gloves/protective clothing/eye protection/face protection.Response:P301 P330 P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.P303 P361 P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing.Rinse skin with water/shower.P304 P340 P315 IF INHALED: Remove person to fresh air and keep comfortable forbreathing. Get immediate medical advice/attention.P305 P351 P338 P315 IF IN EYES: Rinse cautiously with water for several minutes.Remove contact lenses, if present and easy to do. Continue rinsing. Get immediate medicaladvice/attention.P363 Wash contaminated clothing before reuse.P390 Absorb spillage to prevent material damage.Storage:P405 Store locked up.P406 Store in corrosive resistant container with a resistant inner liner.Disposal:P501 Dispose of contents/container in accordance with national regulation.Classification of material C - CorrosiveRisk phrases:R34 Causes burns.R41 Risk of serious damage to eyes.Safety phrases:S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.S28 After contact with skin, wash immediately with plenty of water and soap.S36/37 Wear suitable protective clothing and gloves.S46 If swallowed, seek medical advice immediately and show this container or label.S60 This material and its container must be disposed of as hazardous waste.Dangerous Goods information:Classified as Dangerous Goods according to the criteria of the Australian Code for the Transport of Dangerous Goods by Roadand Rail (ADG Code).Signal word:HAZARDOUSSection 3. Composition / information on ingredientsGeneral chemical description:Type of preparation:MixtureAqueous preparation of:Phosphoric acidAcid

SDS No.: 319297V001.4Page 3 of 10BONDERITE C-IC 33 ACID CLEANER known asALUMIPREP 3320LTIdentity of ingredients:Chemical ingredientsOrthophosphoric acid2-ButoxyethanolPotassium fluorideOctylphenol ethoxylate, 9-10EORemainder not hazardous including water on10- 30 %10- 30 % 3% 1%60- 100 %Section 4. First aid measuresIngestion:Do not induce vomiting.Have victim rinse mouth thoroughly with water.Seek medical advice.Skin:Rinse immediately with plenty of running water (for 10 minutes), seek medical attentionfrom a specialist.Eyes:Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.Get immediate medical attention.Inhalation:If inhaled, immediately remove the affected person to fresh air.Seek medical advice.First Aid facilities:Eye wash and safety showerNormal washroom facilitiesTreat symptomatically.Medical attention and specialtreatment:Section 5. Fire fighting measuresSuitable extinguishing media:Water FogImproper extinguishing media:Water spray jetCombustion behaviour:Non-flammable (aqueous solution).Decomposition products in case of Thermal decomposition can lead to release of irritating gases and vapors.Carbon monoxide.fire::Carbon dioxide.Oxides of phosphorus.Particular danger in case of fire::May react with metals to form flammable hydrogen gas.Special protective equipment forfire-fighters:Wear protective equipment.Wear self-contained breathing apparatus.Additional fire fighting advice:In case of fire, keep containers cool with water spray.Collect contaminated fire fighting water separately. It must not enter drains.Hazchem code:2RSection 6. Accidental release measuresPersonal precautions:Ensure adequate ventilation.Avoid contact with skin and eyes.Wear protective equipment.Keep unprotected persons away.

SDS No.: 319297V001.4Page 4 of 10BONDERITE C-IC 33 ACID CLEANER known asALUMIPREP 3320LTSee advice in section 8Environmental precautions:Do not allow to enter in surface / ground water.Clean-up methods:Absorb spill with inert material. Shovel material into appropriate container for disposal.Section 7. Handling and storagePrecautions for safe handling:Conditions for safe storage:Vapours should be extracted to avoid inhalation.Avoid skin and eye contact.Gloves and safety glasses should be wornSee advice in section 8Avoid naked flames, sparking and sources of ignition.Store in a cool, well-ventilated place.Store in sealed original container.Avoid strong oxidizing agents.Section 8. Exposure controls / personal protectionNational exposure standards:Ingredient [Regulated substance]PHOSPHORIC ACID7664-38-2PHOSPHORIC L111-76-2FLUORIDES (AS F)7789-23-3form ofexposureTWA (ppm)TWA(mg/m3)1Peak Limit.(ppm)-Peak Limit.(mg/m3)-STEL (ppm) ring controls:Ensure good ventilation/suction at the workplace.Eye protection:Wear protective glasses.Skin protection:Suitable protective clothingUse protective gloves made of neoprene, nitrile, polyethylene or PVC, butyl rubber, rubber(natural, latex), PTFEPlease note that in practice the working life of chemical resistant gloves may beconsiderably reduced as a result of many influencing factors (e.g. temperature). Suitablerisk assessment should be carried out by the end user. If signs of wear and tear are noticedthen the gloves should be replaced.Respiratory protection:If inhalation risk exists, wear a respirator or air supplied mask complying with therequirements of AS/NZS 1715 and AS/NZS 1716.Section 9. Physical and chemical propertiesAppearance:Odor:browndarkcharacteristic

SDS No.: 319297V001.4Page 5 of 10BONDERITE C-IC 33 ACID CLEANER known asALUMIPREP 3320LT1.13 - 1.15 g/cm3MiscibleDensity:Solubility in water:Section 10. Stability and reactivityStability:Stable under normal conditions of temperature and pressure.Conditions to avoid:Heat, flames, sparks and other sources of ignition.Incompatible materials:Oxidizing agents.Alkalis.Explosive HYDROGEN GAS may be released if aqueous solutions of this material comeinto contact with reactive metals (IRON, ZINC, ALUMINUM).Hazardous decompositionproducts:Thermal decomposition can lead to release of irritating gases and vapors.Carbon monoxide.Carbon dioxide.Oxides of phosphorus.Section 11. Toxicological informationHealth Effects:Ingestion:Skin:Eyes:Inhalation:This product may produce corrosive damage to the gastrointestinal tract if it is swallowed.Causes burns.Symptoms may include redness, burning, drying, cracking and skin burns.Causes serious eye damage.Contact with the eyes may cause moderate to severe eye injury. Eye contact may result in cornealinjury. Symptoms may include discomfort or pain, excess blinking and tear production, withmarked redness and swelling of the conjunctiva.Vapors may cause severe irritation with possible corrosive burns of the mucous membranes of theupper respiratory tract, conjunctivitis, nasal secretions, sneezing, a burning or tickling sensation inthe nose and throat and retrosternal region, followed by cough, respiratory distress,tracheobronchitis, chemical pneumonitis and possible spasm of the vocal cords, and pulmonaryedema.Acute toxicity:Hazardous componentsCAS-No.Orthophosphoric cutetoxicityestimate(ATE)LD50LD50Value2,600 mg/kg5.1 mg/l1,746 mg/kg2,000 mg/kgRoute peciesMethodratOECD Guideline 423 (AcuteOral toxicity)Expert judgementratrabbitOECD Guideline 401 (AcuteOral Toxicity)

SDS No.: 319297V001.4Page 6 of 10BONDERITE C-IC 33 ACID CLEANER known asALUMIPREP 3320LTSkin corrosion/irritation:Hazardous componentsCAS-No.Orthophosphoric orrosiveExposuretime24 hMethodirritating4hrabbitEU Method B.4 (AcuteToxicity: Dermal Irritation /Corrosion)Exposuretime24 hSpeciesMethodrabbitOECD Guideline 405 (AcuteEye Irritation / Corrosion)Test typeSpeciesMethodnot sensitisingno datahumannot sensitisingGuinea pig guinea pigmaximisation testrabbitSerious eye damage/irritation:Hazardous tatingRespiratory or skin sensitization:Hazardous componentsCAS-No.Orthophosphoric acid7664-38-22-Butoxyethanol111-76-2ResultOECD Guideline 406 (SkinSensitisation)Germ cell mutagenicity:Hazardous componentsCAS-No.ResultType of study /Route ofadministrationbacterialreversemutation assay (e.gAmes test)in vitro mammalianchromosomeaberration testmammalian cellgene mutation assayMetabolicactivation /Exposure timewith and withoutwith and withoutwith and withoutOrthophosphoric ol111-76-2negativenegativenegativebacterialreverse with and withoutmutation assay (e.g with and withoutAmes test)with and withoutin vitro mammalianchromosomeaberration testmammalian cellgene mutation lSpeciesmouseMethodOECDGuideline471(Bacterial Reverse MutationAssay)OECD Guideline 473 (In vitroMammalianChromosomeAberration Test)OECD Guideline 476 (In vitroMammalian Cell GeneMutation Test)OECDGuideline471(Bacterial Reverse MutationAssay)OECD Guideline 473 (In vitroMammalianChromosomeAberration Test)OECD Guideline 476 (In vitroMammalian Cell GeneMutation Test)OECD Guideline 474(Mammalian ErythrocyteMicronucleus Test)

SDS No.: 319297V001.4Page 7 of 10BONDERITE C-IC 33 ACID CLEANER known asALUMIPREP 3320LTRepeated dose toxicity:Hazardous componentsCAS-No.ResultRoute ofapplicationOrthophosphoric acid7664-38-2NOAEL 250mg/kgoral: gavage2-Butoxyethanol111-76-2NOAEL 0.121mg/linhalation2-Butoxyethanol111-76-2NOAEL mg/kg69 oral:drinkingwaterExposure time /Frequency oftreatment6 wdailySpeciesMethodratOECD Guideline 422(Combined Repeated DoseToxicity Study with theReproduction / DevelopmentalToxicity Screening Test)42 or 90 days6hours/day, 5days/week91 dcontinousratratSection 12. Ecological informationOECD Guideline 408(Repeated Dose 90-Day OralToxicity in Rodents)

SDS No.: 319297V001.4Page 8 of 10BONDERITE C-IC 33 ACID CLEANER known asALUMIPREP 3320LTDo not empty into drains / surface water / ground water., Because of the low pH ofthis product, it would be expected to produce significant ecotoxicity upon exposureto aquatic organisms and aquatic systems.General ecological information:Toxicity:Hazardous componentsCAS-No.ValuetypeValueExposuretime 100 mg/lAcuteToxicityStudyFishOrthophosphoric acid7664-38-2LC50Orthophosphoric acid7664-38-2EC50 100 mg/lDaphnia48 hOrthophosphoric acid7664-38-2EC50 100 mg/lAlgae72 hOrthophosphoric acid7664-38-2NOEC100 mg/lAlgae72 hOrthophosphoric acid7664-38-2EC 50270 mg/lBacteria2-Butoxyethanol111-76-2LC501,474 mg/lFish96 h2-Butoxyethanol111-76-2NOEC 100 mg/lFish21 d2-Butoxyethanol111-76-2EC501,550 mg/lDaphnia48 h2-Butoxyethanol111-76-2EC501,840 mg/lAlgae72 h2-Butoxyethanol111-76-2NOEC286 mg/lAlgae72 h2-Butoxyethanol111-76-2Potassium fluoride7789-23-3EC01,000 mg/lBacteria30 minLC50195 mg/lFish240 hPotassium fluoride7789-23-3EC50825 mg/lDaphniaPotassium fluoride7789-23-3EC50290 mg/lAlgae96 hPotassium fluoride7789-23-3EC 502,930 mg/lBacteria3hSpeciesOECD Guideline203 (Fish, AcuteToxicity Test)Daphnia magnaOECD Guideline202 (Daphnia sp.AcuteImmobilisationTest)Desmodesmus subspicatusOECD Guideline201 (Alga, GrowthInhibition Test)Desmodesmus subspicatusOECD Guideline201 (Alga, GrowthInhibition Test)OECD Guideline209 (ActivatedSludge, RespirationInhibition Test)Oncorhynchus mykissOECD Guideline203 (Fish, AcuteToxicity Test)Brachydanio rerio (new name: OECD GuidelineDanio rerio)204 (Fish,Prolonged ToxicityTest: 14-day Study)Daphnia magnaOECD Guideline202 (Daphnia sp.AcuteImmobilisationTest)Pseudokirchnerella subcapitata OECD Guideline201 (Alga, GrowthInhibition Test)Pseudokirchnerella subcapitata OECD Guideline201 (Alga, GrowthInhibition Test)Daphnia sp.Scenedesmus sp.Persistence and degradability:Hazardous componentsCAS-No.ResultRoute ofapplicationMethodDegradabilityMethodOECD Guideline203 (Fish, AcuteToxicity Test)OECD Guideline202 (Daphnia sp.AcuteImmobilisationTest)OECD Guideline201 (Alga, GrowthInhibition Test)ISO 8192 (Test forInhibition ofOxygenConsumption byActivated Sludge)

SDS No.: 319297V001.4Page 9 of 10BONDERITE C-IC 33 ACID CLEANER known asALUMIPREP 3320LT2-Butoxyethanol111-76-2readily biodegradableaerobic73 %EU Method C.4-E (Determinationof the "Ready"BiodegradabilityClosed BottleTest)Bioaccumulative potential / Mobility in soil:Hazardous componentsCAS-No.2-Butoxyethanol111-76-2LogKow Bioconcentrationfactor (BCF)0.81ExposuretimeSpeciesTemperatureMethod25 COECD Guideline 107(Partition Coefficient (noctanol / water), ShakeFlask Method)Section 13. Disposal considerationsWaste disposal of product:Dispose of as hazardous waste in compliance with local and national regulations.Do not allow product to enter sewer or waterways.Recommended cleanser:Clean the packaging with water.Disposal for uncleaned package:Packaging that cannot be cleaned are to be disposed of in the same manner as the product.Section 14. Transport informationRoad and Rail Transport:Dangerous Goods informatio